China solid caustic soda
The main raw material of solid caustic soda is raw salt,and its quality directly affects the quality of the product.China solid caustic soda,with North China,East China,and Central China solid caustic sodaproviding sufficient raw material support for the production of solid caustic soda.In the raw material pretreatment stage,the raw salt needs to undergo processes such as salting and refining to remove impurities such as calcium,magnesium,and sulfate ions,ensuring the purity of the brine.
During the process of salt formation,the original salt is mixed with water to form a saltwater solution,which is then further purified by adding refining agents such as soda ash,caustic soda,and barium chloride to remove impurities from the saltwater.The refined saltwater needs to go through processes such as filtration and neutralization to meet the purity standards required for electrolysis.During this process,strict control is exercised over the temperature,concentration,pH value,and other parameters of the saltwater to ensure the refining effect.
The production process of China solid caustic soda mainly includes key links such as rectification,brine refining,electrolysis,chlorine hydrogen treatment,liquid alkali evaporation,and solid alkali production.
1.Rectification
Rectification is the process of converting alternating current into direct current,providing a stable power source for electrolysis.During the rectification process,AC power is converted into DC power through a rectifier,and then subjected to voltage stabilization,filtering,and other treatments to ensure the stability of the current and voltage required for electrolysis.
2.Saltwater refining
Salt water refining is a key step in ensuring electrolysis efficiency and product quality.The salt water that has undergone desalination and initial refinement needs to undergo secondary refinement to further reduce the calcium and magnesium ion content.Secondary refining usually uses equipment such as chelating ion exchange resin towers to reduce the calcium and magnesium content in saltwater to below 0.002%,ensuring the purity of the electrolyte.
3.Electrolysis
Electrolysis is the core process of China solid caustic soda.In the electrolytic cell,refined saltwater undergoes an electrolytic reaction under the action of direct current,producing sodium hydroxide,chlorine gas,and hydrogen gas.China mainly adopts the ion exchange membrane electrolysis method,which uses a selective ion exchange membrane to separate the anode and cathode chambers,allowing only sodium ions and water to pass through.In the anode,chloride ions lose electrons and generate chlorine gas;In the negative chamber,sodium ions react with water to produce sodium hydroxide and hydrogen gas.The ion exchange membrane electrolysis method has the advantages of low energy consumption,high product purity,and low environmental pollution,and has become the mainstream process for China solid caustic soda.
4.Chlorine hydrogen treatment
Chlorine hydrogen treatment is the process of purifying and treating the chlorine and hydrogen gases generated during the electrolysis process.Chlorine gas is toxic and requires processes such as washing,cooling,drying,and compression to remove impurities and moisture,ensuring its purity and safety.Hydrogen needs to undergo deoxygenation,drying,and other treatments to meet the requirements for subsequent use or storage.
5.Liquid alkali evaporation
Liquid alkali evaporation is the process of concentrating the solid caustic soda solution obtained by electrolysis.By heating,the water in the liquid alkali evaporates,and the concentration of the liquid alkali gradually increases.Liquid alkali evaporation usually uses a multi effect evaporator to improve evaporation efficiency and reduce energy consumption.During the evaporation process,it is necessary to strictly control parameters such as evaporation temperature and vacuum degree to ensure the quality and concentration of liquid alkali.
In the production process of solid caustic soda in China,quality control is a key link to ensure product quality.By establishing a sound quality management system and testing methods,strict quality inspection and control are carried out on raw materials,intermediate products,and finished products.At the same time,strengthen the monitoring and management of the production process,timely discover and solve quality problems in production,and ensure that solid alkali products meet relevant standards and customer requirements.
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